Descripción: Fil:Guevara, J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.

Descripción: Fil:Guevara, J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.

Descripción: An environmental magnetic study of mainly fluvial "postpampean sediments" assigned to the Lujan Formation (Luján, Buenos Aires Province, Argentina) was carried out. The results obtained suggest a depletion of detrital ferromagnetic minerals during the pedogenetic processes. A characteristic magnetic signal can be distinguished in Holocene paleosols and soils of both eolian and fluvial "post-Pampean sediments" (Fm. Luján and Fm. La Postrera . This signal is analogous to that determined in loessic Pampean sediments assigned to the Buenos Aires Formation. It is inferred that the depletion of detrital ferromagnetic minerals is a general process in the Chacopampean area. This process may be associated with the genesis of a superparamagnetic fraction (SP), which could indicate dry periods during the climatic event. The depletion could also be associated with the genesis of a high coercitivy fraction, analogous with those determined in paleosols in the Pampean loess.

Descripción: We report experimental results on the magnetic and transport properties of Ag/Co 90Fe 10 multilayers with variable Ag and Co 90Fe 10 thicknesses. The magnetism samples was characterized by magnetization measurements and ferromagnetic resonance spectroscopy. These measurements show that the magnetic layers are in general composed by single-domain particles and that the shape and the size of the magnetic clusters can be changed by using an applied magnetic field (H dep) on deposition. The resistivity of these multilayered systems is described by a mixed model that includes current-in-plane and current perpendicular plane transport contributions. The transport model proposed to explain the experimental results emphasizes the role played by the magnetic entities on the scattering processes and strongly depends on the silver layer thickness. An electrical percolative transition is observed for samples grown at H dep>H* dep while the magnetic properties of these samples still show a granularlike behavior. © 2004 American Institute of Physics.

Descripción: In the right bank of the Arroyo Tapalqué (Salto de Piedra, Olavarría, Buenos Aires province) is a section through fluvial sediments of the Luján Formation (upper and lower members) and aeolian deposits of La Postrera Formation. A geological and geophysical study was carried out to determination the magnetic parameters of the sediments of both formations, in order to evaluate the environmental and climatic conditions at the time of deposition. Levels with high concentrations of ferromagnetic minerals are thought to be related to an increase in capacity of river transport probably due to higher rainfall. By contrast, a particular magnetic behaviour was detected in levels closely associated with pedogenetic processes (Suelo Puesto Callejón Viejo, SPCV, Suelo Puesto Berrondo, SPB and present soils). This behaviour is attributed to the partial dissolution of the ferromagnetic fraction (magnetic/titanomagnetite) and to possible formation of a high c oercitivity magnetic fraction (hematite?) as an associated process. These results are similar to those obtained for paleosols from the Buenos Aires Formation, probably because of parental material common to both. On the basis of present field and laboratory observations, together with previously available information, a detailed correlation is proposed between features observed in this section and palaeoclimatic fluctuations identified for Pleistocene/Holocene.

Descripción: The use of the magnetic signal of soils and paleosoils as a climatic function. The correlation between an index of potential water storage (PWS) with magnetic signal in soils and paleosoils, developed in loessic sediments has been proposed. The analyzed data suggest the existence of climatic thresholds that affect the genesis, preservation or depletion of ferrimagnetic minerals. Soils and paleosoils characterized by a positive PWS have an appropriate environment that favors the depletion of ferromagnetic minerals due to mainly reductive loss. Such soils are characterized by a depletion of detrital ferrimagnetic minerals, as in northeastern Pampean plain soils and paleosoils of Argentina and SE of China. A negative PWS prevents highly reducing conditions in the soil, and the detrital ferrimagnetic minerals are preserved. On the other hand, the environmental conditions of these soils allow the formation of new nannoparticle minerals. These conditions produce a net magnetic enhancement of the soil, as observed in European soils (Russia, Czech Republic, Rumania), Asian (paleosoils from the loess plateau of China) and Northern African ones (Tunisia). The influence of parent material in the magnetic signal is also discussed.

Descripción: We applied a methodology capable of resolving the optical rotatory power into atomic contributions. The individual atomic contributions to the optical rotatory power and molecular chirality of the methylhydroperoxide are obtained via a canonical transformation of the Hamiltonian by which the electric dipolar moment operator is transformed to the acceleration gauge formalism and the magnetic dipolar moment operator to the torque formalism. The gross atomic isotropic contributions have been evaluated for the carbon, the nonequivalent oxygen, and the nonequivalent hydrogen atoms of methylhydroperoxide, employing a very large Gaussian basis set which is close to the Hartree-Fock limit. © 2008 American Institute of Physics.

Descripción: In the present work, we studied the efficiency of a magnetic island filter for two vacuum arc designs, pulsed and continuous. The magnetic island filter consisted in a straight duct with an external solenoid and a magnet enclosed in a housing (magnetic island) located inside the duct on its axis, and both magnetic fields are in opposite direction. The housing of the magnetic island obstructs the line of sight between the cathode and the substrate. In this arrangement, the charged plasma components move along the curved magnetic field lines, around the magnetic island, but the macroparticles move in straight paths and deposit on the wall of the magnetic island housing. The performance of the filter was characterized for different external and internal field strengths. The plasma transport efficiency was analyzed by measuring the ion saturation current with Langmuir probes and the deposited mass rate. The ion transmission efficiency around the system axis achieved values around 25%. Observation of the coating surface morphology with optical microscopy determined that the macroparticles were effectively removed.

Descripción: The set of 1:1 and 2:1 complexes of XOOX′ (X, X′ H, CH 3) with lithium cation has been studied to determine if they are suitable candidates for chiral discrimination in an isotropic medium via nuclear magnetic resonance spectroscopy. Conventional nuclear magnetic resonance is unable to distinguish between enantiomers in the absence of a chiral solvent. The criterion for experimental detection is valuated by the isotropic part of nuclear shielding polarisability tensors, related to a pseudoscalar of opposite sign for two enantiomers. The study includes calculations at coupled Hartree-Fock and density functional theory schemes for 17O nucleus in each compound. Additional calculations for 1H are also included for some compounds. A huge static homogeneous electric field, perpendicular to the magnetic field of the spectromer, as big as ≈1.7 108 V m -1 should be applied to observe a shift of ≈1 ppm for 17O magnetic shielding in the proposed set of complexes. © 2011 American Institute of Physics.

Descripción: A geological and geophysical study in fluvial post-pampean sediments cropping out on the right bank of the Rio Areco was carried out. The sequence studied comprises the Guerrero and Río Salado members of the Luján Formation, in which three palaeosols are developed. The geophysical studies suggest an impoverishment of the detrital ferrimagnetic minerals (magnetite and titanomagnetite) in the parent material, due to the action of pedogenic processes, accompanied by the generation of two neominerales, one antiferromagnetic and the other ferrimagnetic. The ferrimagnetic mineral consists of particles of ultrafine magnetite (state of superparamagnetic domain, grain size approaching 0.01 μm) formed during periods of excess water. The antiferromagnetic minerals (hematite and/or goethite) were generated in periods of major water deficiency. The presence of these minerals would be indicating a warm and humid climate with a marked dryperiod. The oldest paleosol was developed on the Guerrero Member which correlates with the Puesto Callejón Viejo palaeosol that has an age between 10,000 and 8,000 years AP, in this profile. The Rio Salado Member and the two paleosols developed on it would have developed during the warm period known as, Megathermal, between 9,000 and 7,000 years BP. © 2004 Asociación Geológica Argentina.

Descripción: We present here new paleointensity and geochronology results from Early Cretaceous volcanic rocks of Sierra Chica de Cordoba (Argentina). The new K-Ar isotopic ages of 5 samples range from 136 to 122 Ma. Twenty five samples from 7 individual flows yielded acceptable paleointensity estimates. The mean paleointensity values per flow are ranging from 53.0±1.9 to 25.4±2.6 μT and the corresponding Virtual Dipole Moments (VDMs) are ranging from 9.3±1.3 to 4.6±0.5 (1022 Am2). This corresponds to the mean value of 7.3±1.7x1022 Am2, which is compatible to the present geomagnetic axial dipole. Currently available selected paleointensity data from 80 to 130 Ma suggest that geomagnetic field strength frequently fluctuated before and during the Cretaceous Normal Superchron while the magnetic polarity maintained stable. The mean paleointensities derived from Cordoba lavas agree remarkably well with those obtained from the Parana Magmatic Province (133-132 Ma). This reinforces the hypothesis about the unreliability of ‘Mesozoic Dipole Low'. © 2006, The Seismological Society of Japan, Society of Geomagnetism and Earth, Planetary and Space Sciences, The Volcanological Society of Japan, The Geodetic Society of Japan, The Japanese Society for Planetary Sciences. All rights reserved.