Descripción: This work studies the partitioning of the electron density into two contributions which are interpreted as the paired and the effectively unpaired electron densities. The topological features of each density field as well as of the total density are described localizing the corresponding critical points in simple selected molecules (local formalism). The results show that unpaired electron-density concentrations occur out of the topological bonding regions whereas the paired electron densities present accumulations inside those regions. A comparison of these results with those arising from population analysis techniques (nonlocal or integrated formalisms) is reported. © 2005 American Institute of Physics.

Descripción: This study analyses heating degree-days (HDDs) in Argentina during the period 1900-2008. Gridded temperature data provided by the University of Delaware were analysed to calculate monthly and annual cumulative HDDs. Mean, maximum and minimum values as well as the average duration of the heating season are used to characterize the mean features of the region. Spatial variations are driven by latitude and altitude. The analysis of the temporal distribution of HDDs reveals that the centre of the mean heating season varies from mid-June to mid-July. The length of the cold season grows with increasing latitude and westward with increasing altitude. In the high Andes, the heating season extends all year round. S-mode principal component analysis is used to identify sub-groups of grid points with similar temporal variability. Negative trends in annual cumulative HDDs are detected in most of the country. Linear and nonlinear trends as well as temporal statistics are examined for inter- and intra-annual variability of HDDs to discuss its potential incidence on residential use of natural gas. Seasonal increases in natural gas consumption in the country, including the effect of regional price benefits, could be now better explained not only by population growth but also by the spatial and temporal characterization of the HDD season. © 2012 Royal Meteorological Society.

Descripción: The Centaurs are a transitional population of minor bodies of the solar system and the evolutionary link between the trans-Neptunian objects and the short period comets. The surface properties of these objects are very peculiar, because currently available data suggest that their visual surface colors divide the population into two distinctive groups, those with reddish slopes of the visual reflection spectra and those with neutral spectra. Moreover, some of them are known to posses comas produced by cometary activity. Aims. We aim to investigate possible links between the orbital dynamical history and the surface physical properties of the bodies of this population. Methods. By means of numerical integrations of the equations of motion we calculated the orbital evolution of three groups of Centaurs: the Red group, the Gray group, and the Active group. We looked for statistical differences in the timescales spent by the objects of each group at heliocentric distances below certain values that are associated with locations where certain particular physical processes occur at the surfaces. Results. We find remarkable differences when we compare the fraction of objects that penetrate below typical heliocentric distances for each group. Conclusions. Our results suggest that the observed bimodality in the distribution of surface colors of the Centaurs is caused by the different thermal reprocessing on the surface of bodies of the Red group on one side and the Active and Gray groups on the other. Centaurs of the Gray group likely had cometary activity, therefore their color distribution is similar to that of comet nuclei. © 2012 ESO.

Descripción: A citywide control program of Aedes aegypti (L.) (Diptera: Culicidae) mainly based on the use of larvicides reduced infestations but failed to achieve the desired target levels in Clorinda, northeastern Argentina, over 5 yr of interventions. To understand the underlying causes of persistent infestations and to develop new control tactics adapted to the local context, we conducted two pupal surveys in a large neighborhood with ≈2,500 houses and recorded several variables for every container inspected in fall and spring 2007. In total, 4,076 lots and 4,267 containers were inspected over both surveys, and 8,391 Ae. aegypti pupae were collected. Large tanks used for potable water storage were the most abundant and the most productive type of container, accounting for 6584% of all the pupae collected. Therefore, large tanks were key containers and candidates for improved targeted interventions. Multivariate analysis showed that containers located in the yard, at low sun exposure, unlidded, filled with rain water, and holding polluted water were all more likely to be infested by larvae or pupae. When only infested containers were considered, productivity of pupae was most closely associated with large tanks and rain water. A stochastic simulation model was developed to calculate the expected correlations between pupal and Stegomyia indices according to the characteristics of the distribution of larvae and pupae per container and the spatial scale at which the indices were computed. The correlation between pupal and Stegomyia indices is expected to increase as infestation levels decline. © 2009 Entomological Society of America.