Descripción: The partition function of two hard spheres in a hard-wall pore is studied, appealing to a graph representation. The exact evaluation of the canonical partition function and the one-body distribution function in three different shaped pores are achieved. The analyzed simple geometries are the cuboidal, cylindrical, and ellipsoidal cavities. Results have been compared with two previously studied geometries; the spherical pore and the spherical pore with a hard core. The search of common features in the analytic structure of the partition functions in terms of their length parameters and their volumes, surface area, edges length, and curvatures is addressed too. A general framework for the exact thermodynamic analysis of systems with few and many particles in terms of a set of thermodynamic measures is discussed. We found that an exact thermodynamic description is feasible based on the adoption of an adequate set of measures and the search of the free energy dependence on the adopted measure set. A relation similar to the Laplace equation for the fluid-vapor interface is obtained, which expresses the equilibrium between magnitudes that in extended systems are intensive variables. This exact description is applied to study the thermodynamic behavior of the two hard spheres in a hard-wall pore for the analyzed different geometries. We obtain analytically the external reversible work, the pressure on the wall, the pressure in the homogeneous region, the wall-fluid surface tension, the line tension, and other similar properties. © 2010 American Institute of Physics.

Descripción: The influence of the plankton community structure on carbon dynamics was studied in the surface waters of the Argentinean continental shelf (SW Atlantic Ocean) in summer and fall 2002, 2003 and 2004, The horizontal changes in plankton community respiration (R), net community production (NCP) and gross primary production (GPP) were (1) compared with the difference in the partial pressure of CO2 (pCO2) between the sea surface and the atmosphere (ΔpCO2), (2) compared with oxygen saturation and (3) related to the microscopic phytoplankton assemblages, This area, which has recently been shown to be a CO2 sink, had an average surface oxygen saturation of 108.1%, indicating that net photosynthesis could have played a dominant role in the CO2 dynamics. At most stations, the production:respiration (GPP:R) ratio was greater than 1, indicating that planktonic communities were autotrophic; the average GPP:R ratio for the whole study was 2.99, Phytoplankton biomass (chlorophyll a) and NCP showed an inverse relationship with ΔpCO2 and a direct relationship with %O 2 saturation when phytoplankton assemblages were dominated by diatoms (30% of the stations), This was not the case when small (≤5 μm) flagellates were the most abundant organisms, Although NCP was mostly positive for both groups of stations (i.e. diatom-dominated or small flagellate- dominated), other physical and biological processes are thought to modify the CO2 dynamics when small flagellates are the prevailing phytoplankton group. © Inter-Research 2007.

Descripción: A Singular Value Decomposition (SVD) analysis was performed jointly on extreme temperature events in Argentina and sea surface temperature (SST) in the South Atlantic and South Pacific. Sea level pressure (SLP) patterns associated with the first SVD coupled mode were also analyzed. Winter is the season of the year that is best represented by the first mode, accounting for up to 70% of the winter covariance between temperature events and SST. The warm and cold events in Argentina are essentially a consequence of the creation of meridional atmospheric circulations over the continent. Such atmospheric patterns result from displacements and intensity changes of the subtropical anticyclones over the oceans and of the continental low-pressure center in northwestern Argentina. The temperature events in southern Argentina are also closely related to the warming and cooling of the coastal waters in the South Atlantic and South Pacific. The analysis suggests that in summer and winter, high (low) occurrence of warm events and low (high) occurrence of cold events are related to similar oceanic and atmospheric circulation situations. The temperature events in Argentina show higher correlation with the Atlantic than with the Pacific, which reflects the importance of the "orographic barrier" of the Andes Mountains in driving the atmospheric circulation. The only exception to this rule concerns the warm events in spring, for which the warming of the equatorial Pacific (the ENSO pattern) appears as the dominant mode. The temporal patterns of the temperature events in Argentina exhibit significant interannual variability in fall, winter, and spring, with periods of 3 to 5 years. The summer patterns suggest a very low-frequency variation with a period longer than 20 years. Copyright 2003 by the American Geophysical Union.

Descripción: The scope of the present review focuses on the interfacial properties of cell membranes that may establish a link between the membrane and the cytosolic components. We present evidences that the current view of the membrane as a barrier of permeability that contains an aqueous solution of macromolecules may be replaced by one in which the membrane plays a structural and functional role. Although this idea has been previously suggested, the present is the first systematic work that puts into relevance the relation water-membrane in terms of thermodynamic and structural properties of the interphases that cannot be ignored in the understanding of cell function. To pursue this aim, we introduce a new definition of interphase, in which the water is organized in different levels on the surface with different binding energies. Altogether determines the surface free energy necessary for the structural response to changes in the surrounding media. The physical chemical properties of this region are interpreted in terms of hydration water and confined water, which explain the interaction with proteins and could affect the modulation of enzyme activity. Information provided by several methodologies indicates that the organization of the hydration states is not restricted to the membrane plane albeit to a region extending into the cytoplasm, in which polar head groups play a relevant role. In addition, dynamic properties studied by cyclic voltammetry allow one to deduce the energetics of the conformational changes of the lipid head group in relation to the head-head interactions due to the presence of carbonyls and phosphates at the interphase. These groups are, apparently, surrounded by more than one layer of water molecules: a tightly bound shell, that mostly contributes to the dipole potential, and a second one that may be displaced by proteins and osmotic stress. Hydration water around carbonyl and phosphate groups may change by the presence of polyhydroxylated compounds or by changing the chemical groups esterified to the phosphates, mainly choline, ethanolamine or glycerol. Thus, surface membrane properties, such as the dipole potential and the surface pressure, are modulated by the water at the interphase region by changing the structure of the membrane components. An understanding of the properties of the structural water located at the hydration sites and the functional water confined around the polar head groups modulated by the hydrocarbon chains is helpful to interpret and analyze the consequences of water loss at the membranes of dehydrated cells. In this regard, a correlation between the effects of water activity on cell growth and the lipid composition is discussed in terms of the recovery of the cell volume and their viability. Critical analyses of the properties of water at the interface of lipid membranes merging from these results and others from the literature suggest that the interface links the membrane with the aqueous soluble proteins in a functional unit in which the cell may be considered as a complex structure stabilized by water rather than a water solution of macromolecules surrounded by a semi permeable barrier. © 2008 Elsevier B.V. All rights reserved.

Descripción: In this work we analytically evaluate, for the first time, the exact canonical partition function for two interacting spherical particles into a spherical pore. The interaction with the spherical substrate and between particles is described by an attractive square-well and a square-shoulder potential. In addition, we obtain exact expressions for both the one particle and an averaged two particle density distribution. We develop a thermodynamic approach to few-body systems by introducing a method based on thermodynamic measures [I. Urrutia, J. Chem. Phys. 134, 104503 (2010)] for nonhard interaction potentials. This analysis enables us to obtain expressions for the pressure, the surface tension, and the equivalent magnitudes for the total and Gaussian curvatures. As a by-product, we solve systems composed of two particles outside a fixed spherical obstacle. We study the low density limit for a many-body system confined to a spherical cavity and a many-body system surrounding a spherical obstacle. From this analysis we derive the exact first order dependence of the surface tension and Tolman length. Our findings show that the Tolman length goes to zero in the case of a purely hard wall spherical substrate, but contains a zero order term in density for square-well and square-shoulder wall-fluid potentials. This suggests that any nonhard wall-fluid potential should produce a non-null zero order term in the Tolman length. © 2011 American Institute of Physics.

Descripción: This work is devoted to the exact statistical mechanics treatment of simple inhomogeneous few-body systems. The system of two hard spheres (HSs) confined in a hard spherical pore is systematically analyzed in terms of its dimensionality D. The canonical partition function and the one- and two-body distribution functions are analytically evaluated and a scheme of iterative construction of the D+1 system properties is presented. We analyze in detail both the effect of high confinement, when particles become caged, and the low density limit. Other confinement situations are also studied analytically and several relations between the two HSs in a spherical pore, two sticked HSs in a spherical pore, and two HSs on a spherical surface partition functions are traced. These relations make meaningful the limiting caging and low density behavior. Turning to the system of two HSs in a spherical pore, we also analytically evaluate the pressure tensor. The thermodynamic properties of the system are discussed. To accomplish this statement we purposely focus in the overall characteristics of the inhomogeneous fluid system, instead of concentrate in the peculiarities of a few-body system. Hence, we analyze the equation of state, the pressure at the wall, and the fluid-substrate surface tension. The consequences of new results about the spherically confined system of two HSs in D dimension on the confined many HS system are investigated. New constant coefficients involved in the low density limit properties of the open and closed systems of many HS in a spherical pore are obtained for arbitrary D. The complementary system of many HS which surrounds a HS (a cavity inside of a bulk HS system) is also discussed. © 2010 American Institute of Physics.

Descripción: The thermohaline structure across the tidal fronts of the continental shelf off Patagonia is analyzed using historical and recent summer hydrographic sections. The near-summer tidal front location is determined on the basis of the magnitude of vertical stratification of the water column as measured by the Simpson parameter. Sea surface and air CO2 partial pressures based on data from eleven transects collected in summer and fall from 2000 to 2004 are used to estimate CO2 fluxes over the shelf. The near-shore waters are a source of CO2 to the atmosphere while the midshelf region is a CO2 sink. The transition between source and sink regions closely follows the location of tidal fronts, suggesting a link between vertical stratification of the water column and the regional CO2 balance. The highest surface values of Chl a are associated with the strongest CO2 sinks. The colocation of lowest CO2 partial pressure (pCO2) and highest Chl a suggests that phytoplankton blooms on the stratified side of the fronts draw the ocean's CO2 to very low levels. The mean shelf sea-air difference in pCO2 (ΔpCO2) is -24 μatm and rises to -29 μatm if the shelf break front is included. Peaks in ΔpCO2 of -110 μatm, among the highest observed in the global ocean, are observed. The estimated summer mean CO2 flux over the shelf is -4.4 mmol m-2 d-1 and rises to -5.7 mmol m-2 d-1 when the shelf break area is taken into account. Thus, during the warm season the shelf off Patagonia is a significant atmospheric CO2 sink. Copyright 2005 by the American Geophysical Union.

Descripción: A simple model, previously used to explore wetting transitions, is evaluated for the case of a slab geometry in which adsorption occurs between two semi-infinite solids, with parallel faces separated by a distance L. The model yields a universal description of possible wetting and capillary condensation (CC) transitions. The system’s thermodynamic behavior is predicted from the values of two dimensionless parameters: [Formula Presented] (the reduced gas-surface interaction strength, a function of temperature) and [Formula Presented] (the reduced separation). If [Formula Presented] negligible adsorption occurs at all pressures below saturated vapor pressure (SVP). For somewhat larger values of [Formula Presented] CC occurs for sufficiently small [Formula Presented] close to SVP. For very large values of [Formula Presented] an additional prewetting transition (formation of a film) is predicted for large [Formula Presented] this is accompanied by a CC transition close to SVP. The model is generally consistent with limited results of density-functional calculations for the He liquids at zero temperature. © 1999 The American Physical Society.

Descripción: [i] This work presents results, over the South American region, from the CSIRO Division of Atmospheric Research limited area model (DARLAM) and from the ninelevel general circulation model (GCM) of CSIRO (CSIRO Mk 2), within which it was nested in a one-way mode. Ten separate 30-day DARLAM simulations were performed for both January and July with a resolution of 125 km and were averaged to obtain a climatology for those months. This paper presents for the first time simulations of the January South American climate using a limited area model; previous similar studies simulated only the July climate. The goal of this study was to examine the capability of the CSIRO Mk 2 - DARLAM nested modeling system for simulating the climate in the South American region. Further, it was desired to investigate whether the higher resolution of DARLAM improves the simulated climate over various subregions, compared with the GCM and observations. With this purpose, a representative set of variables was analyzed and statistically compared. Overall, the fields simulated by the nesting system provide a better representation of the South American climate than the GCM. In particular, significant improvements are found in the nested model climatology for near-surface temperature and mean sea level pressure. Comparison of the January and July simulations shows a better wintertime performance. Some significant summertime features, like the Bolivian High, are reasonably well simulated by DARLAM, but not by the GCM. Copyright 2002 by the American Geophysical Union.

Descripción: A Singular value decomposition (SVD) analysis was performed jointly on the daily intensity of extreme rainfall (DIER) over Argentina and the sea surface temperature (SST) of all the oceans from 17.5°N to 90°S in order to identify the large-scale variability of the SSTs related to extreme rainfall, in the period 1962-2005. The main objective of the article is to objectively recognize regions of the tropical and subtropical oceans that could be related with the extreme rainfall over Argentina. Spring is the season that is best represented by the first mode, accounting for up to 45% of the covariance between the DIER and SST. The first SVD mode of spring, summer and autumn presents a pattern of SST relating to the El Niño-Southern Oscillations (ENSO) phenomena with an enhanced DIER in different zones of centre and east of Argentina. In the second SVD mode of spring and summer, the SST patterns show cold conditions in the tropical and subtropical Atlantic and near Indonesia with an enhancement of the DIER in the centre and east of Argentina. These modes show a significant decadal variability. In the third SVD mode of spring and summer, the SST patterns present warm and cold conditions in the Indian Ocean and the centre and western Pacific Ocean (PO) with decreased rainfall in the northern and eastern portion of Argentina, respectively. This mode shows a significant period of temporal variability of around 14 years. The third mode of autumn presents warm conditions in the tropical Atlantic and the southwest PO with a low DIER in the centre and east of Argentina. This mode also presents temporal variability of around 14 years. The correlation between each mode derived from analysis of SVD and climate indices related with SST were computed. © 2012 Royal Meteorological Society.

Descripción: Nickel (Ni) based nanoparticles and nanochains were incorporated as fillers in polydimethylsiloxane (PDMS) elastomers and then these mixtures were thermally cured in the presence of a uniform magnetic field. In this way, macroscopically structured-anisotropic PDMS-Ni based magnetorheological composites were obtained with the formation of pseudo-chains-like structures (referred as needles) oriented in the direction of the applied magnetic field when curing. Nanoparticles were synthesized at room temperature, under air ambient atmosphere (open air, atmospheric pressure) and then calcined at 400°C (in air atmosphere also). The size distribution was obtained by fitting Small Angle X-ray Scattering (SAXS) experiments with a polydisperse hard spheres model and a Schulz-Zimm distribution, obtaining a size distribution centered at (10.0 ± 0.6) nm with polydispersivity given by σ = (8.0 ± 0.2) nm. The SAXS, X-ray powder diffraction, and Transmission Electron Microscope (TEM) experiments are consistent with single crystal nanoparticles of spherical shape (average particle diameter obtained by TEM: (12 ± 1) nm). Nickel-based nanochains (average diameter: 360 nm; average length: 3 μm, obtained by Scanning Electron Microscopy; aspect ratio = length/diameter ∼ 10) were obtained at 85°C and ambient atmosphere (open air, atmospheric pressure). The magnetic properties of Ni-based nanoparticles and nanochains at room temperature are compared and discussed in terms of surface and size effects. Both Ni-based nanoparticles and nanochains were used as fillers for obtaining the PDMS structured magnetorheological composites, observing the presence of oriented needles. Magnetization curves, ferromagnetic resonance (FMR) spectra, and strain-stress curves of low filler's loading composites (2% w/w of fillers) were determined as functions of the relative orientation with respect to the needles. The results indicate that even at low loadings it is possible to obtain magnetorheological composites with anisotropic properties, with larger anisotropy when using nanochains. For instance, the magnetic remanence, the FMR field, and the elastic response to compression are higher when measured parallel to the needles (about 30% with nanochains as fillers). Analogously, the elastic response is also anisotropic, with larger anisotropy when using nanochains as fillers. Therefore, all experiments performed confirm the high potential of nickel nanochains to induce anisotropic effects in magnetorheological materials. © 2013 AIP Publishing LLC.

Descripción: This work presents results, over the South American region, from the CSIRO Division of Atmospheric Research limited area model (DARLAM) and from the ninelevel general circulation model (GCM) of CSIRO (CSIRO Mk 2), within which it was nested in a one-way mode. Ten separate 30-day DARLAM simulations were performed for both January and July with a resolution of 125 km and were averaged to obtain a climatology for those months. This paper presents for the first time simulations of the January South American climate using a limited area model; previous similar studies simulated only the July climate. The goal of this study was to examine the capability of the CSIRO Mk 2 - DARLAM nested modeling system for simulating the climate in the South American region. Further, it was desired to investigate whether the higher resolution of DARLAM improves the simulated climate over various subregions, compared with the GCM and observations. With this purpose, a representative set of variables was analyzed and statistically compared. Overall, the fields simulated by the nesting system provide a better representation of the South American climate than the GCM. In particular, significant improvements are found in the nested model climatology for near-surface temperature and mean sea level pressure. Comparison of the January and July simulations shows a better wintertime performance. Some significant summertime features, like the Bolivian High, are reasonably well simulated by DARLAM, but not by the GCM. Copyright 2002 by the American Geophysical Union.

Descripción: Context. Magnetic clouds (MCs) are formed by magnetic flux ropes that are ejected from the Sun as coronal mass ejections. These structures generally have low plasma beta and travel through the interplanetary medium interacting with the surrounding solar wind. Thus, the dynamical evolution of the internal magnetic structure of a MC is a consequence of both the conditions of its environment and of its own dynamical laws, which are mainly dominated by magnetic forces.Aims. With in-situ observations the magnetic field is only measured along the trajectory of the spacecraft across the MC. Therefore, a magnetic model is needed to reconstruct the magnetic configuration of the encountered MC. The main aim of the present work is to extend the widely used cylindrical model to arbitrary cross-section shapes.Methods. The flux rope boundary is parametrized to account for a broad range of shapes. Then, the internal structure of the flux rope is computed by expressing the magnetic field as a series of modes of a linear force-free field.Results. We analyze the magnetic field profile along straight cuts through the flux rope, in order to simulate the spacecraft crossing through a MC. We find that the magnetic field orientation is only weakly affected by the shape of the MC boundary. Therefore, the MC axis can approximately be found by the typical methods previously used (e.g., minimum variance). The boundary shape affects the magnetic field strength most. The measurement of how much the field strength peaks along the crossing provides an estimation of the aspect ratio of the flux-rope cross-section. The asymmetry of the field strength between the front and the back of the MC, after correcting for the time evolution (i.e., its aging during the observation of the MC), provides an estimation of the cross-section global bending. A flat or/and bent cross-section requires a large anisotropy of the total pressure imposed at the MC boundary by the surrounding medium.Conclusions. The new theoretical model developed here relaxes the cylindrical symmetry hypothesis. It is designed to estimate the cross-section shape of the flux rope using the in-situ data of one spacecraft. This allows a more accurate determination of the global quantities, such as magnetic fluxes and helicity. These quantities are especially important for both linking an observed MC to its solar source and for understanding the corresponding evolution. © 2009 ESO.

Descripción: The heating and acceleration of the solar wind is an active area of research. Alfvén waves, because of their ability to accelerate and heat the plasma, are a likely candidate in both processes. Many models have explored wave dissipation mechanisms which act either in closed or open magnetic field regions. In this work, we emphasize the boundary between these regions, drawing on observations which indicate unique heating is present there. We utilize a new solar corona component of the Space Weather Modeling Framework, in which Alfvén wave energy transport is self-consistently coupled to the magnetohydrodynamic equations. In this solar wind model, the wave pressure gradient accelerates and wave dissipation heats the plasma. Kolmogorov-like wave dissipation as expressed by Hollweg along open magnetic field lines was presented in van der Holst et al. Here, we introduce an additional dissipation mechanism: surface Alfvén wave (SAW) damping, which occurs in regions with transverse (with respect to the magnetic field) gradients in the local Alfvén speed. For solar minimum conditions, we find that SAW dissipation is weak in the polar regions (where Hollweg dissipation is strong), and strong in subpolar latitudes and the boundaries of open and closed magnetic fields (where Hollweg dissipation is weak). We show that SAW damping reproduces regions of enhanced temperature at the boundaries of open and closed magnetic fields seen in tomographic reconstructions in the low corona. Also, we argue that Ulysses data in the heliosphere show enhanced temperatures at the boundaries of fast and slow solar wind, which is reproduced by SAW dissipation. Therefore, the model's temperature distribution shows best agreement with these observations when both dissipation mechanisms are considered. Lastly, we use observational constraints of shock formation in the low corona to assess the Alfvén speed profile in the model. We find that, compared to a polytropic solar wind model, the wave-driven model with physical dissipation mechanisms presented in this work is more aligned with an empirical Alfvén speed profile. Therefore, a wave-driven model which includes the effects of SAW damping is a better background to simulate coronal-mass-ejection-driven shocks. © 2012. The American Astronomical Society. All rights reserved.