N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

En:

Acta Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420

Fecha:

2011

Formato:

application/pdf

Tipo de documento:

info:eu-repo/semantics/article
info:ar-repo/semantics/artículo
info:eu-repo/semantics/publishedVersion

Descriptores:

Asymmetric unit -  Carborane anions -  Carborane cages -  Counterions -  Pyridinium salts -  Title compounds -  Positive ions -  Negative ions

Descripción:

The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.

Identificador(es):

http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez

Derechos:

info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar