A new polymeric phase of zinc(II) oxydiacetate

En:

Acta Crystallogr Sect C Cryst Struct Commun 2003;59(1):m30-m32

Fecha:

2003

Formato:

application/pdf

Tipo de documento:

info:eu-repo/semantics/article
info:ar-repo/semantics/artículo
info:eu-repo/semantics/publishedVersion

Descriptores:

Carboxylic acids -  Crystal structure -  Crystallography -  Hydrogen bonds -  Molecular structure -  Polymers -  Zinc compounds -  Polymeric phases -  Organometallics

Descripción:

A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.

Identificador(es):

http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio

Derechos:

info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar