Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate

En:

Acta Crystallogr Sect C Cryst Struct Commun 1996;52(10):2457-2460

Fecha:

1996

Formato:

application/pdf

Tipo de documento:

info:eu-repo/semantics/article
info:ar-repo/semantics/artículo
info:eu-repo/semantics/publishedVersion

Descriptores:

Crystal atomic structure -  Crystal defects -  Crystallography -  Hydrogen bonds -  Molecular structure -  Zinc compounds -  Aqua ligands -  Octahedral coordination geometry -  Tridentate thiodiacetate ligand

Descripción:

The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.

Identificador(es):

http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio

Derechos:

info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar